The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Aromatic compounds / Aromatic radicals / C6H5 / Ikeda(1985)_300K_225.5-320.0nm

DATAFILE: C6H5_Ikeda(1985)_300K_225.5-320.0nm.txt
NAME: phenyl radical
FORMULA: C6H5
AUTHOR(YEAR): Ikeda(1985)
T: 300K
λ: 225.5-320.0nm
BIBLIOGRAPHY: N. Ikeda, N. Nakashima, and K. Yoshihara, "Observation of the ultraviolet absorption spectrum of phenyl radical in the gas phase", J. Am. Chem. Soc. 107, 3381-3382 (1985); DOI: 10.1021/ja00297a073
COMMENTS: Absorption measurements by nanosecond laser photolysis (excitation of chlorobenzene at 193 nm)

Absorbances have been scaled to σ(250 nm) = (2.75 ± 0.58)×10-17 cm2 molecule-1 by

T.J. Wallington, H. Egsgaard, O.J. Nielsen, J. Platz, J. Sehested, and T. Stein, UV-visible spectrum of the phenyl radical and kinetics of its reaction with NO in the gas phase, Chem. Phys. Lett. 290, 363-370 (1998); DOI: 10.1016/S0009-2614(98)00537-5

The data points plotted in Fig. 3 have been digitized

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